Mixed-Valent Tetranuclear MnIImnIII3 Complex with 1,3-Diamino-2-Hydroxypropane-N,N’,N”,N”’-Tetraacetic Acid
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چکیده
منابع مشابه
Rare tetranuclear mixed-valent [Mn(II)2Mn(IV)2] clusters as building blocks for extended networks.
We report the synthesis of a series of mixed valence Mn(II/IV) tetranuclear clusters [Mn(II)2Mn(IV)2O2(heed)2(EtOH)6Br2]Br2 (1), [Mn(II)2Mn(IV)2O2(heed)2(H2O)2Cl4].2EtOH.H2O (2.2EtOH.H2O), [Mn(II)2Mn(IV)2O2(heed)2(heedH2)2](ClO4)4 (3), [Mn(II)2Mn(IV)2O2(heed)2(MeCN)2(H2O)2(bpy)2](ClO4)4 (4) and [Mn(II)2Mn(IV)2O2(heed)2(bpy)2Br4].2MeOH (5.2MeOH). Clusters 1-5 are constructed from the tripodal li...
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ژورنال
عنوان ژورنال: Chemistry Journal of Moldova
سال: 2014
ISSN: 1857-1727,2345-1688
DOI: 10.19261/cjm.2014.09(1).12